Bonding theories in coordination chemistry

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This question for SKT3023 Inorganic Chemistry

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Elmira Usak

Malaysia

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Bonding theories in coordination chemistry


Froggy Jumps Bonding theories in coordination chemistryVersion en ligne This question for SKT3023 Inorganic Chemistry par Elmira Usak 1 A coordination complex has coordination number of 3. What is the expected geometry of hybrid orbitals? a Tetrahedral b Linear c Trigonal planar 2 When central metal ion has coordination number 6, what type of geometric shape will expected? a b c 3 What coordination number base of the geometric shape? a 1.Octahedral 2. Trigonal Planar 3. Linear b 1. Trigonal planar 2. Octahedral 3. trional Bipyramidal c 1. Linear 2. Trigonal Planar 3. Octahedral 4 Place ligands in spectrochemical series from weaker to stronger field: I-, Br-, Cl-, F-, CN-. a I- < Br- < Cl- < F- < CN- b I- < Cl- < Br- < F- < CN- c CN- < F- < Cl- < Br- < I- 5 The 18-electron rule applies best to which type of complexes? a Organometallic and many low-spin transition-metal complexes b Only high-spin complexes c All coordination compounds 6 Jahn-Teller distortion occurs due to degeneracy in which situations? [Image: Jahn-Teller cartoon] a Only tetrahedral complexes b d9 or other degenerate electronic configurations in octahedral systems c Never occurs in coordination chemistry 7 In octahedral MO theory, which orbitals form the t2g set? a dxy, dxz, dyz b dx2-y2, dz2 c eg set with dxy, dxz, dyz 8 What is Δo in crystal field terms? a Crystall field splitting energy between t2g and eg sets b Ligand field splitting between s and p c Total energy of all electrons in complex 9 Electronic transitions responsible for color in octahedral complexes involve which orbitals? a eg to t2g transitions b t2g to eg transitions c s to p transitions in ligands 10 [Fe(CN)6]4- is typically low-spin or high-spin in CN- field? a Low-spin in the strong CN- field b Cannot be determined from CN- field c High-spin

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Bonding theories in coordination chemistry

Froggy Jumps

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Bonding theories in coordination chemistryVersion en ligne

par Elmira Usak

A coordination complex has coordination number of 3. What is the expected geometry of hybrid orbitals?

When central metal ion has coordination number 6, what type of geometric shape will expected?

What coordination number base of the geometric shape?

Place ligands in spectrochemical series from weaker to stronger field: I-, Br-, Cl-, F-, CN-.

The 18-electron rule applies best to which type of complexes?

Jahn-Teller distortion occurs due to degeneracy in which situations? [Image: Jahn-Teller cartoon]

In octahedral MO theory, which orbitals form the t2g set?

What is Δo in crystal field terms?

Electronic transitions responsible for color in octahedral complexes involve which orbitals?

[Fe(CN)6]4- is typically low-spin or high-spin in CN- field?